FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2042409556> ?p ?o ?g. }

• W2042409556 endingPage "1262" @default.
• W2042409556 startingPage "1247" @default.
• W2042409556 abstract "Abstract The effect of the local ordering of water molecules, adjacent to the molecular surface, on the dynamics of excited state proton transfer to bulk was monitored with the pyranine-γ-CD inclusion complex as a model. The bound pyranine (a commonly used photoacid) exhibits slower dissociation dynamics, with activation energy of the proton dissociation reaction that is significantly higher than that of the reaction of the free pyranine. To understand the source of these modulations of the rate constants, the interaction of the pyranine with the water was investigated by molecular dynamics calculations. The solvation patterns of both; the pyranine and γ-CD, differ in the complex from that of the free compounds. In the case of the pyranine´s hydroxyl, the inclusion in the torus of the γ-CD reduces the number of water molecules in its immediate vicinity and their ordering, thus accounting for the variation in the rates of the proton transfer reactions. On increasing the temperature, the water of the pyranine´s hydroxyl third solvation shell, but not those of the first and the second shell, lose their strict orientation, thus facilitating the dissociation of the pyranine." @default.
• W2042409556 created "2016-06-24" @default.
• W2042409556 creator A5008111351 @default.
• W2042409556 creator A5019758632 @default.
• W2042409556 creator A5022233459 @default.
• W2042409556 creator A5043362829 @default.
• W2042409556 creator A5046611574 @default.
• W2042409556 creator A5074138139 @default.
• W2042409556 date "2008-08-01" @default.
• W2042409556 modified "2023-09-25" @default.
• W2042409556 title "The Effect of Environment on the Dynamics of Proton Dissociation in Water" @default.
• W2042409556 cites W1967119305 @default.
• W2042409556 cites W1967624352 @default.
• W2042409556 cites W1969054385 @default.
• W2042409556 cites W1975174331 @default.
• W2042409556 cites W1980551862 @default.
• W2042409556 cites W1988089293 @default.
• W2042409556 cites W1996487645 @default.
• W2042409556 cites W2003566326 @default.
• W2042409556 cites W2012579886 @default.
• W2042409556 cites W2014875031 @default.
• W2042409556 cites W2016806712 @default.
• W2042409556 cites W2025388437 @default.
• W2042409556 cites W2029667189 @default.
• W2042409556 cites W2029796212 @default.
• W2042409556 cites W2041796632 @default.
• W2042409556 cites W2043626482 @default.
• W2042409556 cites W2046880907 @default.
• W2042409556 cites W2052476167 @default.
• W2042409556 cites W2055036655 @default.
• W2042409556 cites W2057957077 @default.
• W2042409556 cites W2065606160 @default.
• W2042409556 cites W2072685051 @default.
• W2042409556 cites W2079053731 @default.
• W2042409556 cites W2080946383 @default.
• W2042409556 cites W2083755780 @default.
• W2042409556 cites W2085652651 @default.
• W2042409556 cites W2101351503 @default.
• W2042409556 cites W2151548044 @default.
• W2042409556 cites W2169962366 @default.
• W2042409556 cites W2418138498 @default.
• W2042409556 doi "https://doi.org/10.1524/zpch.2008.5386" @default.
• W2042409556 hasPublicationYear "2008" @default.
• W2042409556 type Work @default.
• W2042409556 sameAs 2042409556 @default.
• W2042409556 citedByCount "1" @default.
• W2042409556 countsByYear W20424095562013 @default.
• W2042409556 crossrefType "journal-article" @default.
• W2042409556 hasAuthorship W2042409556A5008111351 @default.
• W2042409556 hasAuthorship W2042409556A5019758632 @default.
• W2042409556 hasAuthorship W2042409556A5022233459 @default.
• W2042409556 hasAuthorship W2042409556A5043362829 @default.
• W2042409556 hasAuthorship W2042409556A5046611574 @default.
• W2042409556 hasAuthorship W2042409556A5074138139 @default.
• W2042409556 hasConcept C102931765 @default.
• W2042409556 hasConcept C121332964 @default.
• W2042409556 hasConcept C147597530 @default.
• W2042409556 hasConcept C147789679 @default.
• W2042409556 hasConcept C148093993 @default.
• W2042409556 hasConcept C149823470 @default.
• W2042409556 hasConcept C159467904 @default.
• W2042409556 hasConcept C178790620 @default.
• W2042409556 hasConcept C185592680 @default.
• W2042409556 hasConcept C2778001640 @default.
• W2042409556 hasConcept C32909587 @default.
• W2042409556 hasConcept C41625074 @default.
• W2042409556 hasConcept C54516573 @default.
• W2042409556 hasConcept C55493867 @default.
• W2042409556 hasConcept C59593255 @default.
• W2042409556 hasConcept C62520636 @default.
• W2042409556 hasConcept C75473681 @default.
• W2042409556 hasConceptScore W2042409556C102931765 @default.
• W2042409556 hasConceptScore W2042409556C121332964 @default.
• W2042409556 hasConceptScore W2042409556C147597530 @default.
• W2042409556 hasConceptScore W2042409556C147789679 @default.
• W2042409556 hasConceptScore W2042409556C148093993 @default.
• W2042409556 hasConceptScore W2042409556C149823470 @default.
• W2042409556 hasConceptScore W2042409556C159467904 @default.
• W2042409556 hasConceptScore W2042409556C178790620 @default.
• W2042409556 hasConceptScore W2042409556C185592680 @default.
• W2042409556 hasConceptScore W2042409556C2778001640 @default.
• W2042409556 hasConceptScore W2042409556C32909587 @default.
• W2042409556 hasConceptScore W2042409556C41625074 @default.
• W2042409556 hasConceptScore W2042409556C54516573 @default.
• W2042409556 hasConceptScore W2042409556C55493867 @default.
• W2042409556 hasConceptScore W2042409556C59593255 @default.
• W2042409556 hasConceptScore W2042409556C62520636 @default.
• W2042409556 hasConceptScore W2042409556C75473681 @default.
• W2042409556 hasIssue "8-9" @default.
• W2042409556 hasLocation W20424095561 @default.
• W2042409556 hasOpenAccess W2042409556 @default.
• W2042409556 hasPrimaryLocation W20424095561 @default.
• W2042409556 hasRelatedWork W1966988844 @default.
• W2042409556 hasRelatedWork W2049601662 @default.
• W2042409556 hasRelatedWork W2071267807 @default.
• W2042409556 hasRelatedWork W2076838474 @default.
• W2042409556 hasRelatedWork W2079087764 @default.
• W2042409556 hasRelatedWork W2116027339 @default.

• next