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• W2042480208 abstract "Rotational transitions of CH3CCSiH3 have been observed in the millimeter-wave region using a computer-controlled source-frequency modulation spectrometer with a 1.8-m-long free space absorption cell. The observed spectrum clearly showed the effect of internal rotation with a small potential barrier. It has been analyzed by calculating the torsion-rotation energies on the basis of torsional wave functions obtained by diagonalizing the torsional part of the Hamiltonian. The least-squares analysis has yielded the rotational constant B = 2068.2817(4) MHz and a few centrifugal distortion constants. The barrier height to internal rotation has been determined to be 3.77(70) cm−1 from the contour map of the standard deviation. Also, the A rotational constant of the silyl group around the symmetry axis has been estimated by fixing the A constant of the methyl group to the value of CH3CCH." @default.
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• W2042480208 date "1985-03-01" @default.
• W2042480208 modified "2023-10-16" @default.
• W2042480208 title "Millimeter-wave spectrum and internal rotation of 1-silylpropyne, CH3CCSiH3" @default.
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• W2042480208 doi "https://doi.org/10.1016/0022-2852(85)90213-9" @default.
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