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- W2042490679 abstract "Reversal of reactivity: A chemoselective direct asymmetric Michael addition of cyclic N-sulfonylimines to α,β-unsaturated aldehydes has been developed by employing chiral iminium catalysis. A tandem base-catalyzed tautomerization of the imine group/hemiaminal formation/dehydroxylation process of the Michael adducts efficiently affords valuable tricyclic piperidine derivatives in moderate to excellent enantioselectivity." @default.
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- W2042490679 date "2011-01-17" @default.
- W2042490679 modified "2023-10-18" @default.
- W2042490679 title "Direct Asymmetric Michael Addition of Cyclic<i>N</i>-Sulfonylimines to α,β-Unsaturated Aldehydes" @default.
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- W2042490679 doi "https://doi.org/10.1002/chem.201002592" @default.
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