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- W2042545295 abstract "An emission system of I2 in Ar in the region 2830–2890 Å is examined under high resolution and found to display fine violet-degraded band structure. This system is interpreted as a charge-transfer transition originating from an ion-pair state near 47 000 cm−1 and terminating on a weakly bound state which dissociates to two ground-state atoms. This interpretation is supported by spectral simulations employing a bound-free model. The transition is tentatively assigned as 0g− → 2431 0u−(3Π), according to which the excited state becomes the fourth ion-pair state near 47 000 cm−1 to be experimentally characterized, and the lower state is the last component of the lowest 3Π state to be identified. The vibrational assignments include about 45 bands in 127I2 and 129I2, spanning v′ = 0–4 and v″ = 6–19, but with the numbering of the lower state remaining uncertain by several units. The main spectroscopic constants for the excited state are Te = 47 070 cm−1, ϵe = 105.7 cm−1, ϵexe = 0.49 cm−1. The spectral simulations place the lower state's potential curve 34 650 cm−1 below the upper state at R = R′e, with slope −850 cm−1/Å. For our “best” numbering of the lower state, ϵe = 20.5 cm−1, ϵexe = 0.29 cm−1, Te = 12 190 cm−1, and De = 360 cm−1." @default.
- W2042545295 created "2016-06-24" @default.
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- W2042545295 date "1983-10-01" @default.
- W2042545295 modified "2023-09-23" @default.
- W2042545295 title "The 2880-Å emission spectrum of I2: Ion-pair states near 47 000 cm−1" @default.
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- W2042545295 doi "https://doi.org/10.1016/0022-2852(83)90134-0" @default.
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