FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W204258575> ?p ?o ?g. }

• W204258575 endingPage "1044" @default.
• W204258575 startingPage "1041" @default.
• W204258575 abstract "Photochemical irradiation of an equimolar mixture of (eta(5)-C(5)H(5))Fe(CO)(2)SiR(3), FpSiR(3), and FpMe leads to the efficient formation of the silicon-carbon coupled product R(3)SiMe, R(3) = Me(3), Me(2)Ph, MePh(2), Ph(3), ClMe(2), Cl(2)Me, Cl(3), Me(2)Ar (Ar = C(6)H(4)X, X = F, OMe, CF(3), NMe(2). Similar chemistry occurs with related germyl and stannyl complexes at slower rates, Si > Ge> >>Sn. Substitution of an aryl hydrogen in FpSiMe(2)C(6)H(4)R' has little effect upon the rate of the reaction whereas progressive substitution of methyl groups on silicon by Cl slows the process. Also changing FpMe to FpCH(2)SiMe(3) dramatically slows the reaction as does the use of (eta(5)-C(5)Me(5))Fe(CO)(2) derivatives. A mechanism involving the initial formation of the 16e(-) intermediate (eta(5)-C(5)H(5))Fe(CO)Me followed by oxidative addition of the Fe-Si bond, accounts for the experimental results obtained." @default.
• W204258575 created "2016-06-24" @default.
• W204258575 creator A5023539152 @default.
• W204258575 creator A5045601765 @default.
• W204258575 creator A5059397107 @default.
• W204258575 creator A5067627796 @default.
• W204258575 date "2010-01-19" @default.
• W204258575 modified "2023-10-07" @default.
• W204258575 title "Formation of Silicon−Carbon Bonds by Photochemical Irradiation of (η⁵-C₅H₅)Fe(CO)₂SiR₃ and (η⁵-C₅H₅)Fe(CO)₂Me to Obtain R₃SiMe" @default.
• W204258575 cites W123896102 @default.
• W204258575 cites W1409719627 @default.
• W204258575 cites W1505974270 @default.
• W204258575 cites W1964570448 @default.
• W204258575 cites W1970428446 @default.
• W204258575 cites W1973728237 @default.
• W204258575 cites W1993743351 @default.
• W204258575 cites W1997673761 @default.
• W204258575 cites W1999991468 @default.
• W204258575 cites W2000586825 @default.
• W204258575 cites W2000977288 @default.
• W204258575 cites W2012173918 @default.
• W204258575 cites W2015520512 @default.
• W204258575 cites W2015834881 @default.
• W204258575 cites W2023345696 @default.
• W204258575 cites W2031319137 @default.
• W204258575 cites W2032626498 @default.
• W204258575 cites W2033620631 @default.
• W204258575 cites W2035769240 @default.
• W204258575 cites W2036788088 @default.
• W204258575 cites W2039950251 @default.
• W204258575 cites W2042309928 @default.
• W204258575 cites W2043886808 @default.
• W204258575 cites W2059530602 @default.
• W204258575 cites W2060036289 @default.
• W204258575 cites W2063591585 @default.
• W204258575 cites W2065128059 @default.
• W204258575 cites W2068717584 @default.
• W204258575 cites W2072719858 @default.
• W204258575 cites W2080172257 @default.
• W204258575 cites W2092340083 @default.
• W204258575 cites W2105989491 @default.
• W204258575 cites W2126669916 @default.
• W204258575 cites W2141679221 @default.
• W204258575 cites W2144323336 @default.
• W204258575 cites W2148795405 @default.
• W204258575 cites W2315711438 @default.
• W204258575 cites W2318477464 @default.
• W204258575 cites W289309775 @default.
• W204258575 doi "https://doi.org/10.1021/om901114q" @default.
• W204258575 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/2840652" @default.
• W204258575 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20305775" @default.
• W204258575 hasPublicationYear "2010" @default.
• W204258575 type Work @default.
• W204258575 sameAs 204258575 @default.
• W204258575 citedByCount "7" @default.
• W204258575 countsByYear W2042585752012 @default.
• W204258575 countsByYear W2042585752014 @default.
• W204258575 countsByYear W2042585752015 @default.
• W204258575 countsByYear W2042585752022 @default.
• W204258575 crossrefType "journal-article" @default.
• W204258575 hasAuthorship W204258575A5023539152 @default.
• W204258575 hasAuthorship W204258575A5045601765 @default.
• W204258575 hasAuthorship W204258575A5059397107 @default.
• W204258575 hasAuthorship W204258575A5067627796 @default.
• W204258575 hasBestOaLocation W2042585752 @default.
• W204258575 hasConcept C104779481 @default.
• W204258575 hasConcept C111337013 @default.
• W204258575 hasConcept C121332964 @default.
• W204258575 hasConcept C140205800 @default.
• W204258575 hasConcept C155647269 @default.
• W204258575 hasConcept C159985019 @default.
• W204258575 hasConcept C161790260 @default.
• W204258575 hasConcept C178790620 @default.
• W204258575 hasConcept C185544564 @default.
• W204258575 hasConcept C185592680 @default.
• W204258575 hasConcept C192562407 @default.
• W204258575 hasConcept C2780263894 @default.
• W204258575 hasConcept C2781076698 @default.
• W204258575 hasConcept C512968161 @default.
• W204258575 hasConcept C544956773 @default.
• W204258575 hasConcept C65024703 @default.
• W204258575 hasConcept C71240020 @default.
• W204258575 hasConcept C75473681 @default.
• W204258575 hasConcept C8010536 @default.
• W204258575 hasConcept C94882840 @default.
• W204258575 hasConceptScore W204258575C104779481 @default.
• W204258575 hasConceptScore W204258575C111337013 @default.
• W204258575 hasConceptScore W204258575C121332964 @default.
• W204258575 hasConceptScore W204258575C140205800 @default.
• W204258575 hasConceptScore W204258575C155647269 @default.
• W204258575 hasConceptScore W204258575C159985019 @default.
• W204258575 hasConceptScore W204258575C161790260 @default.
• W204258575 hasConceptScore W204258575C178790620 @default.
• W204258575 hasConceptScore W204258575C185544564 @default.
• W204258575 hasConceptScore W204258575C185592680 @default.
• W204258575 hasConceptScore W204258575C192562407 @default.
• W204258575 hasConceptScore W204258575C2780263894 @default.
• W204258575 hasConceptScore W204258575C2781076698 @default.

• next