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- W2042589117 abstract "The molecular structure of tetrakis(trifluoromethyl)germane was determined by electron diffraction of gases. The following geometric parameters (r0α values) were obtained: CF = 1.330 ± 0.002 Å, GeC = 1.989 ± 0.005 Å and ∠FCF = 108.0 ± 0.3°. Two very crude models were used to allow for the large amplitude vibrations of the CF3 groups. Both models led essentially to the same result: Td symmetry for the equilibrium configuration of the molecule, i.e. the CF3 groups stagger exactly the GeC bonds, and a torsional force constant for the CF3 groups of approximately 0.04 mdyn Å. CNDO/2 calculations agree surprisingly well with this experimental result." @default.
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- W2042589117 date "1979-01-01" @default.
- W2042589117 modified "2023-10-17" @default.
- W2042589117 title "An electron diffraction study of tetrakis(trifluoromethyl)germane, Ge(CF3)4" @default.
- W2042589117 doi "https://doi.org/10.1016/0022-2860(79)80294-x" @default.
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