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- W2042630578 abstract "Relatively stronger adsorption on silica of proton-donor solutes from mobile phases containing, 1,4-dioxane as the polar modifier is interpreted as a result of an additional adsorption mechanism for the solutes on the monomolecular layer of dioxane molecules which retains some adsorptive properties owing to the presence of external ether groups. A molecular model of adsorption ins ystems of this type is given which takes into account three equilibria: competitive adsorption of the solute molecule on the silica surface, adsorption on the dioxane layer and competitive solvation in the bulk phase. A mathematical equation for the relationship between the retention and the modified concentration is discussed." @default.
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- W2042630578 date "1979-04-01" @default.
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- W2042630578 title "Separation of radioiodine-labelled 2,3,5-triiodobenzoic acid on Sephadex LH-20" @default.
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- W2042630578 doi "https://doi.org/10.1016/s0021-9673(00)91012-4" @default.
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