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• W2042636811 abstract "The molecular structure of the tris(2-mercapto-1-tolylimidazolyl)hydroborato complex {[Tmp-Tol]Zn(mimp-Tol)}[ClO4]·3MeCN has been determined by X-ray diffraction, thereby demonstrating that the mimp-Tol ligand exhibits a N–H⋯O hydrogen bond with the [ClO4]− counterion, {[Tmp-Tol]Zn(mimp-Tol)⋯(OClO3)}, rather than hydrogen bond with a sulfur of the [Tmp-Tol] ligand. DFT calculations on a series of related complexes, namely {[TmMe]Zn(mimMe)}+, {[TmMe]Zn(mimMe)}⋯(OClO3)}, {[TmMe]Zn(mimMe)}⋯[O(H)Me]}+, and {[TmMe]Zn(mimMe)}⋯(NCMe)}+ demonstrate that an intramolecular N–H⋯S hydrogen bond within {[TmMe]Zn(mimMe)}+ is also less favored than the corresponding hydrogen bonding interactions with MeCN, MeOH, and [ClO4]−. The inability of the sulfur atoms of [TmR] ligand to act as an effective hydrogen bond acceptor is in marked contrast to the ability of sulfur atoms in thiolate ligands to participate in the formation of N–H⋯S hydrogen bonds, an observation that reflects the “thione” versus “thiolate” nature of the [TmR] ligand." @default.
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• W2042636811 date "2004-01-01" @default.
• W2042636811 modified "2023-09-23" @default.
• W2042636811 title "The molecular structure of the tris(2-mercapto-1-tolylimidazolyl)hydroborato zinc(2-mercapto-1-tolylimidazole) complex, {[Tm^p-Tol]Zn(mim^p-Tol)}[ClO₄]: intermolecular N–H⋯OClO₃versus intramolecular N–H⋯S hydrogen bonding interactions of the mercaptoimidazole ligand" @default.
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• W2042636811 doi "https://doi.org/10.1039/b412147c" @default.
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