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• W2042648573 abstract "Diiminosuccinonitrile (DISN) has been investigated as a potential prebiotic phosphorylating agent. It is formed readily by the oxidation of diaminomaleonitrile (DAMN), a tetramer of HCN. DISN effects the cyclization of 3'-adenosine monophosphate to adenosine 2',3'-cyclic phosphace in up to 40% yield. The DISN-mediated phosphorylation of uridine to uridine mono-phosphate does not proceed efficiently in aqueous solution. The reaction of DISN and BrCN with uridine-5'-phosphate and uridine results in the formation of 2,2'-anhydronucleotides and 2,2'-anhydronucleosides respectively, and other reaction products resulting from an initial reaction at the 2'- and 3'-hydroxyl groups. The clay mineral catalysis of the cyclization of adenosine-3'-phosphate was investigated using homoionic montmorillonites." @default.
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• W2042648573 date "1983-01-01" @default.
• W2042648573 modified "2023-09-23" @default.
• W2042648573 title "Prebiotic synthesis and reactions of nucleosides and nucleotides" @default.
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• W2042648573 doi "https://doi.org/10.1016/0273-1177(83)90042-x" @default.
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