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- W2042717051 abstract "The IR absorption spectrum of rotationally jet cooled 13CF3I molecules, with vibrational energy near the dissociation threshold D=19000 cm-1, has been measured by using a photodissociation IR spectroscopy method in the range of the nu 1 and nu 4 mode frequencies. A comparison of this spectrum is made with that of 12CF3I. To explain the strong difference observed in the nu 4 mode spectra, a crucial influence of fourth-order Fermi resonance interaction is suggested. The anharmonic shifts appear to be strongly nonlinear with respect to energy." @default.
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- W2042717051 date "1992-11-14" @default.
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- W2042717051 title "Photodissociation IR spectroscopy of vibrationally highly excited13CF3I. Influence of isotopic substitution" @default.
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- W2042717051 doi "https://doi.org/10.1088/0953-4075/25/21/015" @default.
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