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- W2042779188 abstract "This work is concerned with the origin of effects on rate equilibrium processes when reactions are performed in dipolar aprotic media such as dimethyl sulfoxide and dimethyl-formamide compared to typical hydroxylic media. An example of processes studied in our laboratory is the competition between proton abstraction and σ-complex (Meisenheimer adduct) formation in the interaction of nitroaromatic compounds with basic systems (e.g. 1, 3-dinitrobenzene in DMF-D20-Na0D). Other reactions studied are the base catalyzed isotopic exchange of D2 in aqueous DMSO mixtures, and also isotopic exchange of fluoroform. It has been found possible in certain cases to dissect the initial state and transition state contributions to the reaction rates from the kinetically measured enthalpies of activation and the thermodynamically evaluated enthalpies of transfer of the reactants. This procedure affords insight into transition state properties and behaviour." @default.
- W2042779188 created "2016-06-24" @default.
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- W2042779188 date "1980-01-01" @default.
- W2042779188 modified "2023-09-27" @default.
- W2042779188 title "Initial state and transition state solvent effects: Reactions in protic and dipolar aprotic media" @default.
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- W2042779188 doi "https://doi.org/10.1016/s0020-1693(00)92053-x" @default.
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