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- W2042784471 abstract "A high sensitivity spectroscopy is employed to detect vibrational antiitions of ethanol neutrals and ions in a supersonic expansion. The infrared (IR) features located at 3682 and 3667cm−1 can be assigned to the OH stretch for the two neutral C2H5OH conformers, anti and gauche, respectively. Their overtone energies located at 7179 (anti) and 7141(gauche)cm−1 are also identified. The OH fundamental stretch for ethanol ions is redshifted around 210cm−1, while the CH stretch modes are unchanged for neutral and ionic C2H5OH at around 2900–3000cm−1. The charge on the ethanol ion is apparently localized on the oxygen atom. IR induced photodissociation spectroscopy is applied to the study of neutral and protonated ethanol clusters. Neutral and protonated ethanol cluster vibrations are observed. The CH modes are not perturbed by the clustering process. Neutral clusters display only hydrogen bonded OH features, while the protonated ionic clusters display both hydrogen bonded and non-hydrogen-bonded features. These spectroscopic results are analyzed to obtain qualitative structural information on neutral and ionic ethanol clusters." @default.
- W2042784471 created "2016-06-24" @default.
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- W2042784471 date "2006-10-18" @default.
- W2042784471 modified "2023-10-12" @default.
- W2042784471 title "Infrared plus vacuum ultraviolet spectroscopy of neutral and ionic ethanol monomers and clusters" @default.
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- W2042784471 doi "https://doi.org/10.1063/1.2357952" @default.
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