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• W2042808527 abstract "Complexes of the Co(LH)2LX and Co(LH)2- LI·H2O (LH=xanthine or hypoxanthine; XCl, Br) types were synthesized by refluxing 2:1 molar mixtures of LH and CoX2 in triethyl orthoformate-ethyl acetate for one week. Characterization studies suggest that the new complexes are monomeric involving exclusively terminal neutral LH and monoanionic L− ligands. The Co(II) chloride and bromide complexes are tetrahedral (CoN3X chromophores), while the monohydrated Co(II) iodide complexes are pentacoordinated (CoN3IO absorbing species). The hypoxanthine ligands are probably N7-bound to Co(II). In the case of the xanthine complexes, N7 and N9 were considered as about equally likely to function as the primary binding site of the terminal unidentate xanthine ligands." @default.
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• W2042808527 date "1989-07-01" @default.
• W2042808527 modified "2023-09-26" @default.
• W2042808527 title "Xanthine and hypoxanthine complexes with cobalt(II) halides" @default.
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• W2042808527 doi "https://doi.org/10.1016/s0020-1693(00)90110-5" @default.
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