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- W2042819893 abstract "Zeolitic imidazolate frameworks (ZIFs) have received attention for membrane separation applications due to their zeolite-like permanent porosity and tunable uniformly-sized micropores. Although aqueous room temperature synthesis has apparently opened up environmental friendly and efficient ways to synthesize ZIFs, it poses challenges for membrane preparation including unavoidable homogeneous nucleation. Many ZIF membranes prepared in an aqueous system are based on conventional secondary seeded growth techniques for zeolite membranes in spite of well-recognizing that the coordination chemistry of ZIFs is fundamentally different from the covalent chemistry of zeolites. In this study, we first applied a support-surface activation approach to promote heterogeneous nucleation followed by crystal growth in the aqueous system. Continuous well-intergrown ZIF-8 membranes were successfully grown on α-alumina porous support using zinc acetate and showed relatively-high hydrogen permeance of 6.9×10−7 mol/m2 s Pa with corresponding ideal separation selectivity of 13.6 for the hydrogen/methane. The competitive interaction between the coordination of constructing framework and zinc–acetate interaction by carboxylate functionality of acetate anions is essential to control heterogeneous nucleation and membrane growth. Avoiding the seeding process and reducing the use of organic solvents can provide potential for improving a reproducible, scalable, and commercializable process configuration for membrane preparation." @default.
- W2042819893 created "2016-06-24" @default.
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- W2042819893 date "2014-12-01" @default.
- W2042819893 modified "2023-09-27" @default.
- W2042819893 title "Seeding-free aqueous synthesis of zeolitic imidazolate framework-8 membranes: How to trigger preferential heterogeneous nucleation and membrane growth in aqueous rapid reaction solution" @default.
- W2042819893 cites W1966004575 @default.
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- W2042819893 cites W1970952005 @default.
- W2042819893 cites W1971914896 @default.
- W2042819893 cites W1973464595 @default.
- W2042819893 cites W1973946209 @default.
- W2042819893 cites W1975473629 @default.
- W2042819893 cites W1976104104 @default.
- W2042819893 cites W1976122321 @default.
- W2042819893 cites W1984268357 @default.
- W2042819893 cites W1989330616 @default.
- W2042819893 cites W1998167445 @default.
- W2042819893 cites W1998898261 @default.
- W2042819893 cites W2001037711 @default.
- W2042819893 cites W2002487183 @default.
- W2042819893 cites W2002594518 @default.
- W2042819893 cites W2004675181 @default.
- W2042819893 cites W2007353272 @default.
- W2042819893 cites W2010383455 @default.
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- W2042819893 cites W2013151685 @default.
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- W2042819893 cites W2029461239 @default.
- W2042819893 cites W2044259251 @default.
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- W2042819893 doi "https://doi.org/10.1016/j.memsci.2014.08.038" @default.
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