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• W2042833384 abstract "Abstract A silver borate system with the composition 0.7[0.75AgI: 0.25AgCl]: 0.3[ y Ag 2 O:(1 − y )B 2 O 3 ] has been prepared in which the host salt used is a “quenched [0.75AgI: 0.25AgCl] mixed system” instead of the commonly used host AgI. Three sample preparation procedures were adopted: (a) molten sample at ∼ 650°C dropped into neutral liquid bath at ∼ 10°C; (b) molten sample in silica ampule at ∼ 650°C left in air to cool by itself; (c) molten sample left in furnace and allowed to come to room temperature in ∼ 24 h. The highest room temperature conductivity σ ⋍ 2.23 × 10 −2 S cm −1 was obtained for the sample composition: 0.7[0.75AgI: 0.25AgCl]: 0.3[0.833Ag 2 O: 0.167B 2 O 3 ] prepared by procedure “a” and referred to as an “optimal composition”. The DTA, XRD (including linewidth measurement for determining Scherrer length/crystallite size), temperature dependence of σ (by Impedence Spectroscopy), mobility μ (by Transient Ionic Current technique), and number of charge carriers n are also reported. Solid state batteries with the cell configuration: Ag/ 0.7[0.75AgI: 0.25AgCl]: 0.3[0.833Ag 2 O: 0.167B 2 O 3 ]/ (C + I 2 ) were fabricated and the discharge characteristics were studied." @default.
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• W2042833384 date "1996-03-01" @default.
• W2042833384 modified "2023-09-26" @default.
• W2042833384 title "Transport studies on a new fast silver ion conducting system: 0.7[0.75AgI: 0.25AgCl]: 0.3[yAg2O:(1 − y)B2O3]" @default.
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• W2042833384 doi "https://doi.org/10.1016/s0167-2738(96)83005-0" @default.
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