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- W2042931197 abstract "Abstract The kinetics of the reaction of substituted anilines with 2‐chloro‐5‐nitropyridine were studied in dimethyl sulfonide (DMSO) and dimethyl formamide (DMF) at different amine concentrations and temperatures in the range 45–60°C. In both solvents the reaction was not a base‐catalyzed one. A plot of Δ H # versus Δ S # for the reaction in DMSO and DMF gave good straight lines with isokinetic temperatures 128°C and 105°C, respectively. Good linear relationships were obtained from the plots of log k 1 against σ° values at all temperatures with negative ρ values (−1.63 to −1.28 in DMSO) and (−1.26 to −0.90 in DMF). © 2002 Wiley Periodicals, Inc. Int J Chem Kinet 34: 645–650, 2002" @default.
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- W2042931197 date "2002-01-01" @default.
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- W2042931197 title "Kinetics and reactivity of substituted anilines with 2-chloro-5-nitropyridine in dimethyl sulfoxide and dimethyl formamide" @default.
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- W2042931197 doi "https://doi.org/10.1002/kin.10053" @default.
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