Matches in SemOpenAlex for { <https://semopenalex.org/work/W2042943961> ?p ?o ?g. }
Showing items 1 to 88 of
88
with 100 items per page.
- W2042943961 endingPage "447" @default.
- W2042943961 startingPage "431" @default.
- W2042943961 abstract "Rhodium exchange was attempted by using solutions of RhCl3, [Rh(NH3)5Cl]Cl2, and Rh(ClO4)3 in a series of zeolites with decreasing channel size: Y, mordenite, ZSM-34, ZSM-11, erionite, A, and ZK-5. Facile exchange was found in the large-pore zeolites Y and mordenite. Rh is found in the channels and on the surface of the medium-pore zeolites ZSM-34 and ZSM-11, suggesting that both exchange and surface hydrolysis occur. Surface hydrolysis to form islands of what is probably a Rh-oxy-hydroxy hydrate complex appears to be the primary type of deposition on the small-pore zeolites erionite, A, and ZK-5. Exchange in Y with the use of RhCl3(aq) solutions at 90 °C, occurs via the Rh(H2O)63+ complex, does not result in an appreciable Cl− concentration in the zeolite and, contrary to previous work, does not result in Rh on the external surface of the zeolite. RhY prepared from RhCl3(aq) solutions can be used to prepare highly dispersed Rh in Y without the preliminary preoxidative treatment necessary for Rh(NH3)5ClY. Reaction of CO with Rh-exchanged forms of Y, mordenite, ZSM-34, and ZSM-11 produces several species: Rh(I)(CO)2(Oz)2 in mordenite and Y; Rh(I)(CO)2(Oz)(H2O) in all four zeolites; and Rh(I)(CO)3(Oz) in mordenite, ZSM-34, and ZSM-11." @default.
- W2042943961 created "2016-06-24" @default.
- W2042943961 creator A5063380068 @default.
- W2042943961 date "1984-08-01" @default.
- W2042943961 modified "2023-09-25" @default.
- W2042943961 title "Rhodium exchange in zeolites" @default.
- W2042943961 cites W1585625936 @default.
- W2042943961 cites W1965112958 @default.
- W2042943961 cites W1972136943 @default.
- W2042943961 cites W1972810916 @default.
- W2042943961 cites W198363287 @default.
- W2042943961 cites W1987024113 @default.
- W2042943961 cites W1991397094 @default.
- W2042943961 cites W1991989145 @default.
- W2042943961 cites W2000263010 @default.
- W2042943961 cites W2011432206 @default.
- W2042943961 cites W2014003427 @default.
- W2042943961 cites W2037267405 @default.
- W2042943961 cites W2042628929 @default.
- W2042943961 cites W2045709028 @default.
- W2042943961 cites W2057433056 @default.
- W2042943961 cites W2057721391 @default.
- W2042943961 cites W2058142348 @default.
- W2042943961 cites W2068461094 @default.
- W2042943961 cites W2072934353 @default.
- W2042943961 cites W2088980286 @default.
- W2042943961 cites W2100520944 @default.
- W2042943961 cites W2105358364 @default.
- W2042943961 cites W2118802823 @default.
- W2042943961 cites W2150509705 @default.
- W2042943961 cites W2152714968 @default.
- W2042943961 cites W2167590372 @default.
- W2042943961 cites W2327614684 @default.
- W2042943961 cites W2331615624 @default.
- W2042943961 cites W2952885901 @default.
- W2042943961 cites W3136873293 @default.
- W2042943961 doi "https://doi.org/10.1016/0021-9517(84)90021-6" @default.
- W2042943961 hasPublicationYear "1984" @default.
- W2042943961 type Work @default.
- W2042943961 sameAs 2042943961 @default.
- W2042943961 citedByCount "57" @default.
- W2042943961 countsByYear W20429439612014 @default.
- W2042943961 countsByYear W20429439612019 @default.
- W2042943961 crossrefType "journal-article" @default.
- W2042943961 hasAuthorship W2042943961A5063380068 @default.
- W2042943961 hasConcept C117760992 @default.
- W2042943961 hasConcept C145148216 @default.
- W2042943961 hasConcept C161790260 @default.
- W2042943961 hasConcept C178790620 @default.
- W2042943961 hasConcept C179104552 @default.
- W2042943961 hasConcept C185592680 @default.
- W2042943961 hasConcept C2777924179 @default.
- W2042943961 hasConcept C2778077586 @default.
- W2042943961 hasConcept C2778533180 @default.
- W2042943961 hasConcept C521398313 @default.
- W2042943961 hasConcept C94412978 @default.
- W2042943961 hasConceptScore W2042943961C117760992 @default.
- W2042943961 hasConceptScore W2042943961C145148216 @default.
- W2042943961 hasConceptScore W2042943961C161790260 @default.
- W2042943961 hasConceptScore W2042943961C178790620 @default.
- W2042943961 hasConceptScore W2042943961C179104552 @default.
- W2042943961 hasConceptScore W2042943961C185592680 @default.
- W2042943961 hasConceptScore W2042943961C2777924179 @default.
- W2042943961 hasConceptScore W2042943961C2778077586 @default.
- W2042943961 hasConceptScore W2042943961C2778533180 @default.
- W2042943961 hasConceptScore W2042943961C521398313 @default.
- W2042943961 hasConceptScore W2042943961C94412978 @default.
- W2042943961 hasIssue "2" @default.
- W2042943961 hasLocation W20429439611 @default.
- W2042943961 hasOpenAccess W2042943961 @default.
- W2042943961 hasPrimaryLocation W20429439611 @default.
- W2042943961 hasRelatedWork W1501395266 @default.
- W2042943961 hasRelatedWork W1569292563 @default.
- W2042943961 hasRelatedWork W1964485348 @default.
- W2042943961 hasRelatedWork W2001744861 @default.
- W2042943961 hasRelatedWork W2006294062 @default.
- W2042943961 hasRelatedWork W2013928678 @default.
- W2042943961 hasRelatedWork W2153588884 @default.
- W2042943961 hasRelatedWork W229392365 @default.
- W2042943961 hasRelatedWork W2895791145 @default.
- W2042943961 hasRelatedWork W4241413020 @default.
- W2042943961 hasVolume "88" @default.
- W2042943961 isParatext "false" @default.
- W2042943961 isRetracted "false" @default.
- W2042943961 magId "2042943961" @default.
- W2042943961 workType "article" @default.