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- W2042963075 abstract "Piperidone und Piperidinole mit Pyridyl-(2)-Substituenten an C-2 und C-6 bilden Metallchelate mit Salzen zweiwertiger Ubergangsmetalle. In den IR-Spektren dieser Chelate sind die vN—H- sowie die v 8a-Banden des Pyridinrings in charakteristischer Weise verschoben. Daraus folgt, das diese Verbindungen gegenuber dem Metallion als dreizahnige Liganden reagieren. Ruckschlusse auf die Konfiguration der Pyridylsubstituenten werden damit ermoglicht.Piperidones and piperidinols which have pyridyl-(2)-substituents at C-2 and C-6 form metal chelates with salts of bivalent transition metals. In the IR-spectra of these chelates, v N—H and v 8a of the pyridine ring are shifted in a characteristic manner. Therefore, these compounds react as tridentate ligands. From these results, conclusions can be drawn about the configuration of the pyridyl substituents." @default.
- W2042963075 created "2016-06-24" @default.
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- W2042963075 date "1968-01-01" @default.
- W2042963075 modified "2023-09-24" @default.
- W2042963075 title "Metallchelate pyridyl-(2)-substituierter Piperidone und Piperidinole" @default.
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- W2042963075 doi "https://doi.org/10.1002/ardp.19683011005" @default.
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