FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2043006571> ?p ?o ?g. }

• W2043006571 endingPage "1441" @default.
• W2043006571 startingPage "1432" @default.
• W2043006571 abstract "EXAFS spectroscopy has been used to determine the medium-range structural environment (within a radius of 7 A) of trace levels of Zn2+ ions within the octahedral sheets of trioctahedral 2:1 phyllosilicates. EXAFS signatures of trace quantities (800–4000 ppm) of Zn in natural and synthetic trioctahedral 2:1 phyllosilicates (talcs and biotite) were analyzed using ab initio FEFF calculations (FEFF 8.10 code) in which various second-neighbor atomic configurations around a Zn-containing octahedral site were examined. Comparison of the results of these model calculations with observed Zn K -edge EXAFS spectra provides constraints on the distribution of Zn within the octahedral sheet. Zn was found to be randomly distributed within the octahedral sheets of the synthetic talc containing 4000 ppm Zn. In the natural biotite containing 800 ppm Zn, the distribution of Zn could not be determined because of significant Fe content, which precluded unambiguous FEFF analysis. Finally, FEFF analysis of single-scattering and multiple-scattering contributions to the EXAFS data of the Zn-dilute talc sample, followed by comparison with EXAFS data from a natural dioctahedral illite sample containing 140 ppm Zn, allowed unambiguous identification of spectral features characteristic of Zn2+ ions incorporated within the octahedral sheets of trioctahedral phyllosilicates. These results indicate that EXAFS spectroscopy can be used to distinguish between incorporation of trace levels of Zn2+ ions within the octahedral sheet of di- or trioctahedral phyllosilicates. They also provide a strong basis for determining the speciation of Zn at trace concentration levels in natural phyllosilicates from Zn-contaminated soils and sediments using Zn K -edge EXAFS spectroscopy. Because the crystal chemistry of other potentially toxic first-row divalent transition elements (i.e., Co2+, Ni2+, and Cu2+) is similar to that of Zn2+, this FEFF-based EXAFS approach could be used to (1) complement existing FTIR and polarized-EXAFS approaches in assessing the distribution of these elements within the octahedral sheets of di- and trioctahedral plyllosilicates and (2) better determine the speciation of these elements in contaminated soils and sediments." @default.
• W2043006571 created "2016-06-24" @default.
• W2043006571 creator A5002171426 @default.
• W2043006571 creator A5033529192 @default.
• W2043006571 creator A5041206946 @default.
• W2043006571 creator A5046867572 @default.
• W2043006571 creator A5079031027 @default.
• W2043006571 date "2006-08-01" @default.
• W2043006571 modified "2023-09-25" @default.
• W2043006571 title "EXAFS signature of structural Zn at trace levels in natural and synthetic trioctahedral 2:1 phyllosilicates" @default.
• W2043006571 cites W1821151640 @default.
• W2043006571 cites W1964799795 @default.
• W2043006571 cites W1968908434 @default.
• W2043006571 cites W1973255514 @default.
• W2043006571 cites W1982689190 @default.
• W2043006571 cites W1998850350 @default.
• W2043006571 cites W2000834561 @default.
• W2043006571 cites W2001603968 @default.
• W2043006571 cites W2008108524 @default.
• W2043006571 cites W2018222553 @default.
• W2043006571 cites W2041722087 @default.
• W2043006571 cites W2041821136 @default.
• W2043006571 cites W2046396675 @default.
• W2043006571 cites W2068867138 @default.
• W2043006571 cites W2096604414 @default.
• W2043006571 cites W2102955145 @default.
• W2043006571 cites W2113222140 @default.
• W2043006571 cites W2125399803 @default.
• W2043006571 cites W2127597975 @default.
• W2043006571 cites W2131035164 @default.
• W2043006571 cites W2134692642 @default.
• W2043006571 cites W2140777719 @default.
• W2043006571 cites W2148190334 @default.
• W2043006571 cites W2150203495 @default.
• W2043006571 cites W2158378070 @default.
• W2043006571 cites W2162059183 @default.
• W2043006571 cites W2167590372 @default.
• W2043006571 cites W2184646761 @default.
• W2043006571 cites W2213453795 @default.
• W2043006571 cites W2318352220 @default.
• W2043006571 cites W2396632992 @default.
• W2043006571 cites W2410351663 @default.
• W2043006571 cites W2590370713 @default.
• W2043006571 cites W2601311254 @default.
• W2043006571 cites W2910890078 @default.
• W2043006571 cites W3132515255 @default.
• W2043006571 cites W3143442556 @default.
• W2043006571 cites W37799611 @default.
• W2043006571 cites W613841769 @default.
• W2043006571 cites W2808452546 @default.
• W2043006571 doi "https://doi.org/10.2138/am.2006.1923" @default.
• W2043006571 hasPublicationYear "2006" @default.
• W2043006571 type Work @default.
• W2043006571 sameAs 2043006571 @default.
• W2043006571 citedByCount "16" @default.
• W2043006571 countsByYear W20430065712012 @default.
• W2043006571 countsByYear W20430065712013 @default.
• W2043006571 countsByYear W20430065712014 @default.
• W2043006571 countsByYear W20430065712015 @default.
• W2043006571 countsByYear W20430065712016 @default.
• W2043006571 countsByYear W20430065712017 @default.
• W2043006571 countsByYear W20430065712019 @default.
• W2043006571 countsByYear W20430065712022 @default.
• W2043006571 countsByYear W20430065712023 @default.
• W2043006571 crossrefType "journal-article" @default.
• W2043006571 hasAuthorship W2043006571A5002171426 @default.
• W2043006571 hasAuthorship W2043006571A5033529192 @default.
• W2043006571 hasAuthorship W2043006571A5041206946 @default.
• W2043006571 hasAuthorship W2043006571A5046867572 @default.
• W2043006571 hasAuthorship W2043006571A5079031027 @default.
• W2043006571 hasConcept C107861141 @default.
• W2043006571 hasConcept C119824511 @default.
• W2043006571 hasConcept C120665830 @default.
• W2043006571 hasConcept C121332964 @default.
• W2043006571 hasConcept C127313418 @default.
• W2043006571 hasConcept C138885662 @default.
• W2043006571 hasConcept C151730666 @default.
• W2043006571 hasConcept C17409809 @default.
• W2043006571 hasConcept C185592680 @default.
• W2043006571 hasConcept C199289684 @default.
• W2043006571 hasConcept C2524010 @default.
• W2043006571 hasConcept C2776608160 @default.
• W2043006571 hasConcept C2779696439 @default.
• W2043006571 hasConcept C33923547 @default.
• W2043006571 hasConcept C41895202 @default.
• W2043006571 hasConcept C75291252 @default.
• W2043006571 hasConceptScore W2043006571C107861141 @default.
• W2043006571 hasConceptScore W2043006571C119824511 @default.
• W2043006571 hasConceptScore W2043006571C120665830 @default.
• W2043006571 hasConceptScore W2043006571C121332964 @default.
• W2043006571 hasConceptScore W2043006571C127313418 @default.
• W2043006571 hasConceptScore W2043006571C138885662 @default.
• W2043006571 hasConceptScore W2043006571C151730666 @default.
• W2043006571 hasConceptScore W2043006571C17409809 @default.
• W2043006571 hasConceptScore W2043006571C185592680 @default.
• W2043006571 hasConceptScore W2043006571C199289684 @default.
• W2043006571 hasConceptScore W2043006571C2524010 @default.
• W2043006571 hasConceptScore W2043006571C2776608160 @default.

• next