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• W2043042831 abstract "An inexpensive low-temperature aqueous thin film processing technique is presented for the fabrication of large two-dimensional (2-D) arrays of α-Cr2O3 without template, surfactant, or applied external field. The arrays consist of well-defined, monodispersed, and noninteracting crystalline spherical mesoparticles (250 nm) that are grown directly onto single crystalline silicon wafers (Si or SiO2) or polycrystalline transparent conducting oxide (TCO) substrates by heteronucleation. Their UV−visible optical absorption properties are consistent with the electronic transitions of Cr3+ ions in D3d symmetry but significantly blue-shifted compared to single crystal or polydispersed α-Cr2O3 samples. Such arrays could be of interest for theoretical and experimental studies of the unique nonreciprocal optical effects observed in α-Cr2O3." @default.
• W2043042831 created "2016-06-24" @default.
• W2043042831 creator A5029139156 @default.
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• W2043042831 date "2003-03-01" @default.
• W2043042831 modified "2023-09-24" @default.
• W2043042831 title "2-D Mesoparticulate Arrays of α-Cr₂O₃" @default.
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• W2043042831 doi "https://doi.org/10.1021/jp026933u" @default.
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