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- W2043075375 abstract "Supercritical carbon dioxide (scCO2) is a unique reaction medium for the selective hydrogenation of cinnamaldehyde using a well-defined Ru–Pt bimetallic catalyst supported on MCM-48. The reaction is completely selective to the unsaturated alcohol in supercritical carbon dioxide. The selectivity to the desired unsaturated alcohol shows a significant pressure dependence. By varying the pressure at the constant reaction temperature of 323 K, we are able to optimize the selectivity of cinnamyl alcohol to 100%. This is a particularly dramatic enhancement compared to that in organic solvents and under solventless conditions, where Ru–Pt bimetallic catalyst produces cinnamyl alcohol along with hydrocinnamaldehyde and 3-phenylpropanol. More importantly, the excellent physicochemical properties of the scCO2 medium provide a significant influence on the selectivity, which goes beyond that of simple solvent replacement only." @default.
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- W2043075375 date "2003-02-11" @default.
- W2043075375 modified "2023-10-18" @default.
- W2043075375 title "Completely selective hydrogenation of trans-cinnamaldehyde to cinnamyl alcohol promoted by a Ru–Pt bimetallic catalyst supported on MCM-48 in supercritical carbon dioxide" @default.
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- W2043075375 doi "https://doi.org/10.1039/b210161k" @default.
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