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- W2043079844 abstract "Me3Sn−NCN−R1 (R1 = SiiPr3, SiPh2tBu, Ph) reacts with Cp2TiCl2 (Cp = η5-C5H5) or Cp*2TiCl2 (Cp* = η5-C5Me5) selectively at the Sn−N bond to give the corresponding bis(carbodiimido)titanium complexes (Cp2Ti(NCN−SiR3)2, Cp*2Ti(NCN−SiR3)2, and Cp2Ti(NCN−Ph)2) in moderate to high yields. The structure of Cp2Ti(NCN−Ph)2 was determined by X-ray crystallography. Oligomeric complexes were formed by the reaction of Me3Sn−NCN−X−NCN−SnMe3 (X = −C6H3Cl−CH2−C6H3Cl−) with Cp*2TiCl2." @default.
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- W2043079844 date "1998-06-01" @default.
- W2043079844 modified "2023-09-30" @default.
- W2043079844 title "Synthesis of Carbodiimidotitanium Complexes by the Reaction of (Trimethylstannyl)carbodiimides with Titanium Chlorides" @default.
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- W2043079844 doi "https://doi.org/10.1021/om971129t" @default.
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