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• W2043101670 endingPage "5714" @default.
• W2043101670 startingPage "5701" @default.
• W2043101670 abstract "Abstract The synthesis of enantiopure (+)‐benzotricamphor syn ‐ 5 , an important chiral C 3 ‐symmetric rigid building block for supramolecular applications, was studied in detail to reduce the number of steps and to increase the diastereoselectivity and overall yield. The new synthetic procedure allowed larger amounts of syn ‐ 5 to be obtained and used for the preparation of new derivatives, such as the corresponding tris ‐trifluoromethanesulfonate syn ‐ 12 , which was efficiently transformed into (+)‐benzotribornenetrinitrile syn ‐ 1 and (+)‐benzotribornenetris(ethynyl‐4‐pyridine) syn ‐ 2 . The previously reported (+)‐benzotricamphortrioxime syn ‐ 6 was transformed into tris‐nitrile syn ‐ 3 by Beckman reaction. Compounds syn ‐ 1 – 3 were employed as multidentate ligands for silver(I) and platinum(II) centres in apolar solvents. The linear coordination geometry of Ag I and square‐planar geometry of cis ‐chelated Pt II in combination with the chiral tripodal ligands syn ‐ 1 – 3 led to the formation of chiral enantiopure capsules with M 3 L 2 stoichiometry, as confirmed by 2D NMR NOESY and DOSY experiments as well as ESI mass spectrometry." @default.
• W2043101670 created "2016-06-24" @default.
• W2043101670 creator A5009657855 @default.
• W2043101670 creator A5036914375 @default.
• W2043101670 creator A5038586419 @default.
• W2043101670 creator A5054270405 @default.
• W2043101670 creator A5057798067 @default.
• W2043101670 creator A5068388742 @default.
• W2043101670 date "2013-02-27" @default.
• W2043101670 modified "2023-10-18" @default.
• W2043101670 title "Chiral M₃L₂Self-Assembled Capsules through Metal Coordination of Enantiopure Ligating Benzocyclotrimers: NMR Spectroscopic and ESI Mass Spectrometric Investigation" @default.
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