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• W2043104570 abstract "We have performed soft x-ray emission spectroscopy (SXES) and soft x-ray absorption spectroscopy (SXAS) experiments on aluminum hydride $ensuremath{alpha}$-AlH${}_{3}$. The occupied and unoccupied electronic states of the Al 3$p$ partial density of states are obtained experimentally. By comparing the data from Al metal and $ensuremath{alpha}$-AlH${}_{3}$, a band gap with a few eV is found for $ensuremath{alpha}$-AlH${}_{3}$. In addition, the occupied states of $ensuremath{alpha}$-AlH${}_{3}$ have a larger spectral intensity than that of Al metal, indicating an increase in the number of electrons with the Al 3$p$ character through Al-H bond formations. The results of a band-structure calculation account for the formation of the energy gap and the increase of the Al 3$p$ electrons qualitatively. This suggests that a covalent-like nature is important to the Al-H bond in $ensuremath{alpha}$-AlH${}_{3}$." @default.
• W2043104570 created "2016-06-24" @default.
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• W2043104570 date "2011-10-10" @default.
• W2043104570 modified "2023-10-15" @default.
• W2043104570 title "Electronic structure of aluminium trihydride studied using soft x-ray emission and absorption spectroscopy" @default.
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• W2043104570 doi "https://doi.org/10.1103/physrevb.84.153102" @default.
• W2043104570 hasPublicationYear "2011" @default.
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