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- W2043132465 abstract "Abstract An expedient method for the stereoselective preparation of musclide A1, A2 and B, cardiotonic-potentiating principles from musk, has been achieved. The key step is the addition of the O -benzyl ethers of prop-2-yn-1-ol and ( R )-but-3-yn-2-ol to aldehydes mediated by zinc triflate, Et 3 N, and (+)- or (−)- N -methylephedrine. In some cases, the partial reduction of the resulting alkynols to Z -olefins has allowed us to remove the minor stereoisomer easily by chromatography to afford highly stereoenriched precursors of musclides." @default.
- W2043132465 created "2016-06-24" @default.
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- W2043132465 date "2003-05-01" @default.
- W2043132465 modified "2023-09-26" @default.
- W2043132465 title "Stereoselective synthesis of musclides A1, A2 and B" @default.
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- W2043132465 doi "https://doi.org/10.1016/s0957-4166(03)00120-4" @default.
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