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• W2043137327 abstract "The electrocatalytic oxidation of hydrazine in basic solution at glassy carbon (gc) electrodes modified with a thin layer of polymeric cobalt phthalocyanines is described. Cyclic voltammetry (cv) in aqueous media yields a well-defined chemically irreversible anodic wave (Ep = −0.30 V vs. sce at pH 13), and peak currents for this process vary linearly with the square root of scan rate. Limiting currents measured at a rotating disk electrode are independent of the film thickness at a given substrate concentration; linear Levich plots are obtained under all experimental conditions used. Evaluation of the available data in light of the Savéant model for electrocatysis at polymer-modified electrodes suggests that the kinetics of the net 4e- -process is controlled by the diffusion of substrate from bulk solution to the solution/polymer interface." @default.
• W2043137327 created "2016-06-24" @default.
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• W2043137327 date "1994-12-01" @default.
• W2043137327 modified "2023-09-24" @default.
• W2043137327 title "Electro-oxidation of hydrazine at electrodes modified with polymeric cobalt phthalocyanine" @default.
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• W2043137327 doi "https://doi.org/10.1016/0013-4686(94)00228-2" @default.
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