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• W2043148911 abstract "${text{K}}_{2}{text{MgWO}}_{2}{({text{PO}}_{4})}_{2}$ ferroelectric single crystal, derived from ${text{KTiOPO}}_{4}$ (KTP) by replacement of two ${text{Ti}}^{4+}$ ions with ${text{Mg}}^{2+}$ and ${text{W}}^{6+}$ cations, was investigated at ambient pressure by micro-Raman scattering and infrared spectroscopies with a focus on polarization properties of vibrational modes. These results were analyzed based on classical lattice dynamics calculations which allowed to propose the normal-mode symmetries and assignments. In addition to the ambient pressure studies, high-pressure Raman scattering studies were performed. These studies showed the onset of a reversible first-order phase transition near 2.0 GPa which is associated with marked softening of the low wave number mode corresponding to motions of the ${text{K}}^{+}$ ions. The structural changes at the phase transition are relatively weak and either the crystal exhibits transformation from the ambient pressure P1 to a high-pressure monoclinic structure or there is no symmetry change at the phase transition, i.e., this transition is isosymmetric." @default.
• W2043148911 created "2016-06-24" @default.
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• W2043148911 creator A5059702222 @default.
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• W2043148911 date "2008-08-26" @default.
• W2043148911 modified "2023-10-18" @default.
• W2043148911 title "Lattice dynamics and high-pressure Raman scattering studies of ferroelectric<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mtext>K</mml:mtext><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mrow><mml:mtext>MgWO</mml:mtext></mml:mrow><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mrow><mml:mrow><mml:mo>(</mml:mo><mml:mrow><mml:msub><mml:mrow><mml:mtext>PO</mml:mtext></mml:mrow><mml:mn>4</mml:mn></mml:msub></mml:mrow><mml:mo>)</mml:mo></mml:mrow></mml:…" @default.
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• W2043148911 doi "https://doi.org/10.1103/physrevb.78.064116" @default.
• W2043148911 hasPublicationYear "2008" @default.
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