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• W2043182043 endingPage "2358" @default.
• W2043182043 startingPage "2352" @default.
• W2043182043 abstract "A high-nitrogen energetic salt, 1-amino-1-hydrazino-2,2-dinitroethylene guanidine salt [G(AHDNE)], was synthesized by reacting of 1-amino-1-hydrazino-2,2-dinitroethylene (AHDNE) and guanidine hydrochloride in sodium hydroxide aqueous solution. The theoretical investigation on G(AHDNE) was carried out by B3LYP/<TEX>$6-311+G^*$</TEX> method. The thermal behaviors of G(AHDNE) were studied with DSC and TG-DTG methods, and the result presents an intense exothermic decomposition process. The enthalpy, apparent activation energy and pre-exponential constant of the process are <TEX>$-1060J;g^{-1}$</TEX>, <TEX>$148.7kJ;mol^{-1}$</TEX> and <TEX>$10^{15.90}s^{-1}$</TEX>, respectively. The critical temperature of thermal explosion of G(AHDNE) is <TEX>$152.63^{circ}C$</TEX>. The specific heat capacity of G(AHDNE) was studied with micro-DSC method and theoretical calculation method, and the molar heat capacity is <TEX>$314.69J;mol^{-1}K^{-1}$</TEX> at 298.15 K. Adiabatic time-to-explosion of G(AHDNE) was calculated to be a certain value between 60-72 s. The detonation velocity and detonation pressure were also estimated. G(AHDNE) presents good performances." @default.
• W2043182043 created "2016-06-24" @default.
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• W2043182043 date "2012-07-20" @default.
• W2043182043 modified "2023-10-10" @default.
• W2043182043 title "Structural and Thermal Characteristics of a High-Nitrogen Energetic Material: G(AHDNE)" @default.
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• W2043182043 doi "https://doi.org/10.5012/bkcs.2012.33.7.2352" @default.
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