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• W2043201384 startingPage "1812" @default.
• W2043201384 abstract "Two routes to the 2,6-dideoxysugar methyl trioxacarcinoside A are described. Each was enabled by an apparent α-chelation-controlled addition of an allylmetal reagent to a ketone substrate containing a free α-hydroxyl group and a β-hydroxyl substituent, either free or protected as the corresponding di-tert-butylmethyl silyl ether. Both routes provide practical access to gram quantities of trioxacarcinose A in a form suitable for glycosidic coupling reactions." @default.
• W2043201384 created "2016-06-24" @default.
• W2043201384 creator A5009206100 @default.
• W2043201384 creator A5019576209 @default.
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• W2043201384 date "2012-03-09" @default.
• W2043201384 modified "2023-09-26" @default.
• W2043201384 title "Diastereoselective Additions of Allylmetal Reagents to Free and Protected <i>syn</i>-<b>α,β</b>-Dihydroxyketones Enable Efficient Synthetic Routes to Methyl Trioxacarcinoside A" @default.
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• W2043201384 doi "https://doi.org/10.1021/ol300377a" @default.
• W2043201384 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3328101" @default.
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