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- W2043256912 abstract "Retention of stereochemistry: p-Methoxybenzylic trifluoroborate salts react with aldehydes in the presence of Lewis or Brønsted acids to give homoallylic alcohols with concomitant dearomatisation of the aromatic ring (see scheme). Using enantioenriched benzylic trifluoroborate salts leads to adducts with >98 % retention of the stereochemistry in most cases. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W2043256912 date "2010-08-17" @default.
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- W2043256912 title "Benzylic Boron Reagents Behaving as Allylic Boron Reagents towards Aldehydes: A New Asymmetric Reaction Leading to Homoallylic Alcohols with Concomitant Dearomatisation" @default.
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- W2043256912 doi "https://doi.org/10.1002/chem.201001174" @default.
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