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• W2043283336 startingPage "094303" @default.
• W2043283336 abstract "Rate constants for the dissociation of OH−(H2O) and OH−(H2O)2 by transfer of electronic energy from O2(a1Δg) were measured. Values of 1.8×10−11 and 2.2×10−11 cm3 molecule−1 s−1, respectively, at 300 K were derived and temperature dependences were obtained from 300 to 500 K for OH−(H2O) and from 300 to 400 K for OH−(H2O)2. Dissociative excitation transfer with OH−(H2O) is slightly endothermic and the reaction appears to have a positive temperature dependence, but barely outside the uncertainty range. In contrast, the reaction of OH−(H2O)2 is exothermic and appears to have a negative temperature dependence. The rate constants are analyzed in terms of unimolecular rate theory, which suggests that the dissociation is prompt and is not affected by collisions with the helium buffer gas." @default.
• W2043283336 created "2016-06-24" @default.
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• W2043283336 date "2009-01-01" @default.
• W2043283336 modified "2023-10-16" @default.
• W2043283336 title "Dissociative excitation transfer in the reaction of O[sub 2](a[sup 1]Δ[sub g]) with OH[sup −](H[sub 2]O)[sub 1,2] clusters" @default.
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• W2043283336 doi "https://doi.org/10.1063/1.3212839" @default.
• W2043283336 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19739854" @default.
• W2043283336 hasPublicationYear "2009" @default.
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