FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2043286317> ?p ?o ?g. }

• W2043286317 endingPage "5519" @default.
• W2043286317 startingPage "5503" @default.
• W2043286317 abstract "Abstract A new family in town! Treatment of a rare‐earth metal (Ln) and either a potential divalent rare‐earth metal (Ln′) or an alkaline earth metal (Ae) with 2,6‐diphenylphenol (HOdpp) at elevated temperatures (200–250 °C) afforded heterobimetallic aryloxo complexes (see figure). Both a charge‐separated species, [(Ln′/Ae) 2 (Odpp) 3 ][Ln(Odpp) 4 ], and a neutral species, [AeEu(Odpp) 4 ], were obtained and crystallographically characterised. magnified image Treatment of a rare earth metal (Ln) and a potential divalent rare earth metal (Ln′) or an alkaline earth metal (Ae) with 2,6‐diphenylphenol (HOdpp) at elevated temperatures (200–250 °C) afforded heterobimetallic aryloxo complexes, which were structurally characterised. A charge‐separated species [(Ln′/Ae) 2 (Odpp) 3 ][Ln(Odpp) 4 ] was obtained for a range of metals, demonstrating the similarities between the chemistry of the divalent rare earth metals and the alkaline earth metals. The [(Ln′/Ae) 2 (Odpp) 3 ] + cation in the heterobimetallic structures is unusual in that it consists solely of bridging aryloxide ligands. A molecular heterobimetallic species [AeEu(Odpp) 4 ] (Ae=Ca, Sr, Ba) was obtained by treating an alkaline earth metal and Eu metal with HOdpp at elevated temperatures. Similarly, [BaSr(Odpp) 4 ] was prepared by treating Ba metal and Sr metal with HOdpp. Treatment of [Ba 2 (Odpp) 4 ] with [Mg(Odpp) 2 (thf) 2 ] in toluene afforded [Ba 2 (Odpp) 3 ][Mg(Odpp) 3 (thf)]. Analogous solution‐based syntheses were not possible for [(Ln′/Ae) 2 (Odpp) 3 ][Ln(Odpp) 4 ] complexes, for which the free‐metal route was essential. As a result of the absence of additional donor ligands, the crystal structures of the heterobimetallic complexes feature extensive π‐Ph–metal interactions involving the pendant phenyl groups of the Odpp ligands, thus enabling the large electropositive metal atoms to attain coordination saturation. The charge‐separated heterobimetallic species were purified by extraction with toluene/thf mixtures at ambient temperature (Ba‐containing compounds) or by extraction with toluene under pressure above the boiling point of the solvent (other products). In donor solvents, heterobimetallic complexes other than those containing barium were found to fragment into homometallic species." @default.
• W2043286317 created "2016-06-24" @default.
• W2043286317 creator A5033890830 @default.
• W2043286317 creator A5051339653 @default.
• W2043286317 creator A5064617775 @default.
• W2043286317 creator A5068724810 @default.
• W2043286317 creator A5070036826 @default.
• W2043286317 creator A5041552224 @default.
• W2043286317 date "2009-05-19" @default.
• W2043286317 modified "2023-10-09" @default.
• W2043286317 title "Charge‐Separated and Molecular Heterobimetallic Rare Earth–Rare Earth and Alkaline Earth–Rare Earth Aryloxo Complexes Featuring Intramolecular Metal–π‐arene Interactions" @default.
• W2043286317 cites W1606906340 @default.
• W2043286317 cites W1966721775 @default.
• W2043286317 cites W1966760157 @default.
• W2043286317 cites W1967799039 @default.
• W2043286317 cites W1968042459 @default.
• W2043286317 cites W1970389839 @default.
• W2043286317 cites W1979848967 @default.
• W2043286317 cites W1980217637 @default.
• W2043286317 cites W1982465083 @default.
• W2043286317 cites W1983079360 @default.
• W2043286317 cites W1983759499 @default.
• W2043286317 cites W1989849227 @default.
• W2043286317 cites W1992713260 @default.
• W2043286317 cites W1993322056 @default.
• W2043286317 cites W1998165290 @default.
• W2043286317 cites W2005357799 @default.
• W2043286317 cites W2013299343 @default.
• W2043286317 cites W2024012831 @default.
• W2043286317 cites W2033050068 @default.
• W2043286317 cites W2033521840 @default.
• W2043286317 cites W2036161907 @default.
• W2043286317 cites W2036309081 @default.
• W2043286317 cites W2041124487 @default.
• W2043286317 cites W2043681509 @default.
• W2043286317 cites W2046232422 @default.
• W2043286317 cites W2054159422 @default.
• W2043286317 cites W2057599720 @default.
• W2043286317 cites W2065116881 @default.
• W2043286317 cites W2066441773 @default.
• W2043286317 cites W2067825636 @default.
• W2043286317 cites W2071451948 @default.
• W2043286317 cites W2073052334 @default.
• W2043286317 cites W2073195392 @default.
• W2043286317 cites W2077411171 @default.
• W2043286317 cites W2079265484 @default.
• W2043286317 cites W2080468716 @default.
• W2043286317 cites W2086926345 @default.
• W2043286317 cites W2089239938 @default.
• W2043286317 cites W2091085928 @default.
• W2043286317 cites W2091240623 @default.
• W2043286317 cites W2101258722 @default.
• W2043286317 cites W2112010031 @default.
• W2043286317 cites W2117429640 @default.
• W2043286317 cites W2118445000 @default.
• W2043286317 cites W2121554426 @default.
• W2043286317 cites W212193479 @default.
• W2043286317 cites W2140210354 @default.
• W2043286317 cites W2144332006 @default.
• W2043286317 cites W2144815499 @default.
• W2043286317 cites W2162175736 @default.
• W2043286317 cites W2167590372 @default.
• W2043286317 cites W2315043638 @default.
• W2043286317 cites W2318505093 @default.
• W2043286317 cites W2329559897 @default.
• W2043286317 cites W2399010029 @default.
• W2043286317 cites W2951635037 @default.
• W2043286317 cites W2952701071 @default.
• W2043286317 cites W4239096475 @default.
• W2043286317 cites W4243365592 @default.
• W2043286317 doi "https://doi.org/10.1002/chem.200900229" @default.
• W2043286317 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19360834" @default.
• W2043286317 hasPublicationYear "2009" @default.
• W2043286317 type Work @default.
• W2043286317 sameAs 2043286317 @default.
• W2043286317 citedByCount "46" @default.
• W2043286317 countsByYear W20432863172012 @default.
• W2043286317 countsByYear W20432863172013 @default.
• W2043286317 countsByYear W20432863172014 @default.
• W2043286317 countsByYear W20432863172015 @default.
• W2043286317 countsByYear W20432863172016 @default.
• W2043286317 countsByYear W20432863172017 @default.
• W2043286317 countsByYear W20432863172018 @default.
• W2043286317 countsByYear W20432863172019 @default.
• W2043286317 countsByYear W20432863172020 @default.
• W2043286317 countsByYear W20432863172021 @default.
• W2043286317 countsByYear W20432863172022 @default.
• W2043286317 crossrefType "journal-article" @default.
• W2043286317 hasAuthorship W2043286317A5033890830 @default.
• W2043286317 hasAuthorship W2043286317A5041552224 @default.
• W2043286317 hasAuthorship W2043286317A5051339653 @default.
• W2043286317 hasAuthorship W2043286317A5064617775 @default.
• W2043286317 hasAuthorship W2043286317A5068724810 @default.
• W2043286317 hasAuthorship W2043286317A5070036826 @default.
• W2043286317 hasConcept C121332964 @default.
• W2043286317 hasConcept C145148216 @default.
• W2043286317 hasConcept C178790620 @default.
• W2043286317 hasConcept C179104552 @default.

• next