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- W2043286923 abstract "The steric and electronic influences of substituents attached to the 1,2-dicarbonyl system on the success of the reaction of 1,2- diketones with dimethyl 3-ketoglutarate 2 have been examined. It is clear from the reaction of 2 with benzil, thienil, furil, and phenanthrenequinone 5, respectively, coupled with 13C NMR spectroscopy of the reaction intermediates, that steric effects play a major role in the overall success of the reaction to provide 4. This is analogous to the situation observed earlier with 1,2-diketones, R-CO-CO-R, where R represented an aliptiatic or alicyclic group." @default.
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- W2043286923 date "1985-01-01" @default.
- W2043286923 modified "2023-10-15" @default.
- W2043286923 title "Studies on the reaction of 1,2-dicarbonyl compounds with dimethyl 3-ketoglutarate. Steric and electronic effects" @default.
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- W2043286923 doi "https://doi.org/10.1016/s0040-4039(00)98951-2" @default.
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