FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2043288843> ?p ?o ?g. }

• W2043288843 endingPage "771" @default.
• W2043288843 startingPage "759" @default.
• W2043288843 abstract "We report the synthesis and gradient stimuli-responsive properties of cyclodextrin-overhanging hyperbranched core-double-shell miktoarm architectures. A ionic hyperbranched poly(β-cyclodextrin) (β-CD) core was firstly synthesized via a convenient “A2+B3” approach. Double-layered shell architectures, composed of poly(N-isopropyl acrylamide) (PNIPAm) and poly(N,N-dimethylaminoethyl methacrylate) (PDMAEMA) miktoarms as the outermost shell linked to poly(N,N-diethylaminoethyl methacrylate) (PDEAEMA) homoarms which form the inner shell, were obtained by a sequential atom transfer radical polymerization (ATRP) and parallel click chemistry from the modified hyperbranched poly(β-CD) macroinitiator. The combined characterization by 1H NMR, 13C NMR, 1H-29Si heteronuclear multiple-bond correlation (HMBC), FTIR and size exclusion chromatography/multiangle laser light scattering (SEC/MALLS) confirms the remarkable hyperbranched poly(β-CD) core and double-shell miktoarm architectures. The gradient triple-stimuli-responsive properties of hyperbranched core-double-shell miktoarm architectures and the corresponding mechanisms were investigated by UV–vis spectrophotometer and dynamic light scattering (DLS). Results show that this polymer possesses three-stage phase transition behaviors. The first-stage phase transition comes from the deprotonation of PDEAEMA segments at pH 9–10 aqueous solution under room temperature. The confined coil-globule conformation transition of PNIPAm and PDMAEMA arms gives rise to the second-stage hysteretic cophase transition between 38 and 44 °C at pH 10. The third-stage phase transition occurs above 44 °C at pH = 10 attributed to the confined secondary conformation transition of partial PDMAEMA segments. This cyclodextrin-overhanging hyperbranched core-double-shell miktoarm architectures are expected to solve the problems of inadequate functionalities from core layer and lacking multiresponsiveness for shell layers existing in the dendritic core-multishell architectures. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012" @default.
• W2043288843 created "2016-06-24" @default.
• W2043288843 creator A5000574920 @default.
• W2043288843 creator A5017001198 @default.
• W2043288843 creator A5032354328 @default.
• W2043288843 creator A5033568110 @default.
• W2043288843 creator A5034493918 @default.
• W2043288843 creator A5037812252 @default.
• W2043288843 creator A5073660249 @default.
• W2043288843 date "2011-11-26" @default.
• W2043288843 modified "2023-09-27" @default.
• W2043288843 title "Cyclodextrin-overhanging hyperbranched core-double-shell miktoarm architectures: Synthesis and gradient stimuli-responsive properties" @default.
• W2043288843 cites W1683433992 @default.
• W2043288843 cites W1963644590 @default.
• W2043288843 cites W1964963209 @default.
• W2043288843 cites W1971144013 @default.
• W2043288843 cites W1972004666 @default.
• W2043288843 cites W1981261119 @default.
• W2043288843 cites W1981642984 @default.
• W2043288843 cites W1982977246 @default.
• W2043288843 cites W1986153952 @default.
• W2043288843 cites W2000011083 @default.
• W2043288843 cites W2005254566 @default.
• W2043288843 cites W2005358158 @default.
• W2043288843 cites W2009004781 @default.
• W2043288843 cites W2012930640 @default.
• W2043288843 cites W2015625297 @default.
• W2043288843 cites W2020088067 @default.
• W2043288843 cites W2021568609 @default.
• W2043288843 cites W2029629786 @default.
• W2043288843 cites W2031773818 @default.
• W2043288843 cites W2033573965 @default.
• W2043288843 cites W2033750870 @default.
• W2043288843 cites W2035056336 @default.
• W2043288843 cites W2036568496 @default.
• W2043288843 cites W2038506143 @default.
• W2043288843 cites W2044588436 @default.
• W2043288843 cites W2049087408 @default.
• W2043288843 cites W2051839424 @default.
• W2043288843 cites W2053810326 @default.
• W2043288843 cites W2060282649 @default.
• W2043288843 cites W2065088375 @default.
• W2043288843 cites W2068009464 @default.
• W2043288843 cites W2070247593 @default.
• W2043288843 cites W2080195231 @default.
• W2043288843 cites W2081766886 @default.
• W2043288843 cites W2081943249 @default.
• W2043288843 cites W2085465573 @default.
• W2043288843 cites W2088732135 @default.
• W2043288843 cites W2091681397 @default.
• W2043288843 cites W2092176214 @default.
• W2043288843 cites W2092700187 @default.
• W2043288843 cites W2100432804 @default.
• W2043288843 cites W2107432357 @default.
• W2043288843 cites W2113594717 @default.
• W2043288843 cites W2136109198 @default.
• W2043288843 cites W2142768440 @default.
• W2043288843 cites W2145117476 @default.
• W2043288843 cites W2327577931 @default.
• W2043288843 doi "https://doi.org/10.1002/pola.25831" @default.
• W2043288843 hasPublicationYear "2011" @default.
• W2043288843 type Work @default.
• W2043288843 sameAs 2043288843 @default.
• W2043288843 citedByCount "6" @default.
• W2043288843 countsByYear W20432888432012 @default.
• W2043288843 countsByYear W20432888432013 @default.
• W2043288843 countsByYear W20432888432015 @default.
• W2043288843 crossrefType "journal-article" @default.
• W2043288843 hasAuthorship W2043288843A5000574920 @default.
• W2043288843 hasAuthorship W2043288843A5017001198 @default.
• W2043288843 hasAuthorship W2043288843A5032354328 @default.
• W2043288843 hasAuthorship W2043288843A5033568110 @default.
• W2043288843 hasAuthorship W2043288843A5034493918 @default.
• W2043288843 hasAuthorship W2043288843A5037812252 @default.
• W2043288843 hasAuthorship W2043288843A5073660249 @default.
• W2043288843 hasConcept C120665830 @default.
• W2043288843 hasConcept C121332964 @default.
• W2043288843 hasConcept C131888329 @default.
• W2043288843 hasConcept C132050475 @default.
• W2043288843 hasConcept C14631669 @default.
• W2043288843 hasConcept C150539798 @default.
• W2043288843 hasConcept C155672457 @default.
• W2043288843 hasConcept C159985019 @default.
• W2043288843 hasConcept C171250308 @default.
• W2043288843 hasConcept C178790620 @default.
• W2043288843 hasConcept C185592680 @default.
• W2043288843 hasConcept C188027245 @default.
• W2043288843 hasConcept C191486275 @default.
• W2043288843 hasConcept C192562407 @default.
• W2043288843 hasConcept C2779433975 @default.
• W2043288843 hasConcept C44228677 @default.
• W2043288843 hasConcept C521977710 @default.
• W2043288843 hasConceptScore W2043288843C120665830 @default.
• W2043288843 hasConceptScore W2043288843C121332964 @default.
• W2043288843 hasConceptScore W2043288843C131888329 @default.
• W2043288843 hasConceptScore W2043288843C132050475 @default.
• W2043288843 hasConceptScore W2043288843C14631669 @default.
• W2043288843 hasConceptScore W2043288843C150539798 @default.

• next