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- W2043292037 abstract "Abstract The new nickel selenite chloride, Ni5(SeO3)4Cl2, was obtained by high-temperature solid state reaction of NiCl2, Ni2O3 and SeO2 in a 1:2:4 molar ratio at 700 °C in an evacuated quartz tube. Its structure was established by single-crystal X-ray diffraction. Ni5(SeO3)4Cl2 crystallizes in the triclinic system, space group P-1 (No. 2) with cell parameters of a=8.076(2), b=9.288(2), c=9.376(2) A, α=101.97(3), β = 105.60 ( 3 ) , γ = 91.83 ( 3 ) ° and Z = 2 . All nickel(II) ions in Ni5(SeO3)4Cl2 are octahedrally coordinated by selenite oxygens or/and chloride anions (([Ni(1)O5Cl], [Ni(2)O4Cl2], [Ni(3)O5Cl], [Ni(4)O6] and [Ni(5)O4Cl]). The structure of the title compound features a condensed three-dimensional (3D) network built by Ni(II) ions interconnected by SeO32− anions as well as Cl− anions. Magnetic property measurements show strong antiferromagnetic interaction between nickel(II) ions." @default.
- W2043292037 created "2016-06-24" @default.
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- W2043292037 date "2005-09-01" @default.
- W2043292037 modified "2023-09-24" @default.
- W2043292037 title "Synthesis, crystal structure and magnetic property of a new nickel selenite chloride: Ni5(SeO3)4Cl2" @default.
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- W2043292037 doi "https://doi.org/10.1016/j.jssc.2005.07.005" @default.
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