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- W2043293844 abstract "A series of water-soluble alkylaminopentamethylcyclopentadienyliron dicarbonyl complexes, [Cp∗(CO)2Fe{NH2(CH2)nCH3}]BF4 (n = 2–6; Cp∗ = η5-C5Me5) and the diaminopropane bridged complex, [{Cp∗(CO)2Fe}2{μ-NH2(CH2)3NH2}](BF4)2 have been synthesized and fully characterized. [Cp∗(CO)2Fe{NH2(CH2)5CH3}]BF4 undergoes counteranion exchange with sodium tetraphenylborate in both aqueous and organic media to give water insoluble [Cp∗(CO)2Fe{NH2(CH2)5CH3}]BPh4. The molecular structures for compounds [Cp∗(CO)2Fe{NH2(CH2)3CH3}]BF4 and [{Cp∗(CO)2Fe}2{μ-NH2(CH2)3NH2}](BF4)2 have been determined by single crystal X-ray crystallography and show that they crystallize in the orthorhombic and monoclinic crystal systems, respectively." @default.
- W2043293844 created "2016-06-24" @default.
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- W2043293844 date "2012-03-01" @default.
- W2043293844 modified "2023-10-18" @default.
- W2043293844 title "Synthesis, characterization and structural elucidation of water-soluble 1-aminoalkane and α,ω-diaminoalkane complexes of the pentamethylcyclopentadienyliron dicarbonyl cation, [Cp∗(CO)2Fe]+" @default.
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- W2043293844 doi "https://doi.org/10.1016/j.ica.2011.09.058" @default.
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