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• W2043301702 abstract "Using photoelectron spectroscopy, the interface formation of anatase and rutile TiO2 with RuO2 and tin-doped indium oxide (ITO) is studied. It is consistently found that the valence band maximum of rutile is 0.7 ± 0.1 eV above that of anatase. The alignment is confirmed by electronic structure calculations, which further show that the alignment is related to the splitting of the energy bands formed by the O 2pz lone-pair orbitals. The alignment can explain the different electron concentrations in doped anatase and rutile and the enhanced photocatalytic activity of mixed phase particles." @default.
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• W2043301702 date "2013-11-25" @default.
• W2043301702 modified "2023-10-01" @default.
• W2043301702 title "Energy Band Alignment between Anatase and Rutile TiO₂" @default.
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• W2043301702 doi "https://doi.org/10.1021/jz402165b" @default.
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