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- W2043317859 abstract "Abstract The time evolution of the 2537 A sensitised luminescence of mercury vapour has been examined at 304 K. With a trace of N 2 to generate Hg(6 3 P o ) and an excess of Ar to chaperon dimer formation, full time profiles of the ultraviolet and green bands have been recorded. The ultraviolet emission is of much shorter duration than the green with these gas mixtures. The reservoir of the ultraviolet band is the O − u state of the mercury dimer which correlates with Hg(6 3 P o ), Hg(6 1 S o ) and is generated in the combination of metastable and ground-state mercury atoms. The Hg 2 O − u is efficiently relaxed to the O ± g firstexcited states of the dimer in collision with Hg atoms, but rather inefficiently in collisions with Ar atoms. The rate coefficient for formation of excited trimers in the reaction Hg 2 O ± g + Hg(6 1 S o ) + N 2 → Hg * 3 + N 2 has been recorded as 1.95(±0.1) × 10 −30 cm 6 molecule −2 s −1 at 304 K." @default.
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- W2043317859 date "1980-03-01" @default.
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- W2043317859 title "Combination of metastable and ground-state mercury atoms into ungerade dimer states" @default.
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- W2043317859 doi "https://doi.org/10.1016/0009-2614(80)85320-6" @default.
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