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• W2043376656 abstract "Phase separation in ternary monotectic alloys ${({mathrm{Al}}_{0.345}{mathrm{Bi}}_{0.655})}_{90}{X}_{10}$ ($X=mathrm{Cu},mathrm{Si},mathrm{Sn}$; wt %) has been investigated. Experimental work included differential scanning calorimetry and measurements of the liquid-liquid $(ltext{ensuremath{-}}l)$ interfacial tension and difference in densities of coexisting phases. It is established that the interfacial tension between Al-rich and Bi-rich liquid phases increases when either Cu or Si is added and it decreases when Sn is added to the ${mathrm{Al}}_{34.5}{mathrm{Bi}}_{65.5}$ binary. This is related to the size of miscibility gap and is explained by increasing composition gradient across the $(ltext{ensuremath{-}}l)$ interface upon addition of either Cu or Si and its decreasing upon addition of Sn to the Al-Bi binary. The drop of interfacial tension in liquid ${({mathrm{Al}}_{0.345}{mathrm{Bi}}_{0.655})}_{90}{mathrm{Sn}}_{10}$ against ${mathrm{Al}}_{34.5}{mathrm{Bi}}_{65.5}$ is also caused by adsorption of Sn at the interface. Temperature dependences of the interfacial tension and density difference in the alloys studied follow a power law in reduced temperature $({T}_{C}ensuremath{-}T)$ at approach of the critical point with exponents close to the values predicted by the renormalization group theory of critical behavior." @default.
• W2043376656 created "2016-06-24" @default.
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• W2043376656 date "2008-03-26" @default.
• W2043376656 modified "2023-09-26" @default.
• W2043376656 title "Characteristics of liquid-liquid immiscibility in Al-Bi-Cu, Al-Bi-Si, and Al-Bi-Sn monotectic alloys: Differential scanning calorimetry, interfacial tension, and density difference measurements" @default.
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• W2043376656 doi "https://doi.org/10.1103/physrevb.77.125426" @default.
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