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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2043421145> ?p ?o ?g. }

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• W2043421145 abstract "The core structure of the RNA polymerase inhibitor tagetitoxin has been synthesized by one-carbon ring expansion of bridged bicyclic monothioacetals. The key steps are intramolecular ylide formation by reaction between the sulfur atom and a pendant diazoester, followed by an efficient photochemical 1,2-rearrangement to give the desired 9-oxa-3-thiabicyclo[3.3.1]nonane ring system." @default.
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• W2043421145 date "2008-10-31" @default.
• W2043421145 modified "2023-09-27" @default.
• W2043421145 title "Synthesis of the Tagetitoxin Core via Photo-Stevens Rearrangement" @default.
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• W2043421145 doi "https://doi.org/10.1021/ol802297h" @default.
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