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- W2043445008 abstract "Novel carbon self-doped TiO2 sheets (CTS) with exposed {001} facets were synthesized by hydrothermal treatment of titanium carbide (TiC) in a HNO3-HF mixed aqueous solution. In this synthesis TiC was used as a precursor of TiO2 and a source of C, which was self-doped into the lattice of anatase sheets. The resulting CTS materials were examined as photocatalysts for degradation of methylene blue (MB) in aqueous solutions under visible light irradiation (λ > 420 nm). These materials exhibited an enhanced absorption in the whole visible-light region and an obvious red shift at the absorption edges. The first-principle density functional theory (DFT) calculations provided a further confirmation for the aforementioned red shift and for noticeable reduction of the band gap of C-doped TiO2 sheets with exposed {001} facets. The photocatalytic studies of CTS showed that these sheets exhibited much higher photocatalytic activity than that of the C-doped TiO2 nanoparticles due to the presence of exposed {001} facets. In addition, separation of CTS after photocatalytic reaction from slurry by filtration or sedimentation and their reuse is easier in comparison to conventional nanosized powder photocatalysts." @default.
- W2043445008 created "2016-06-24" @default.
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- W2043445008 date "2011-01-01" @default.
- W2043445008 modified "2023-10-17" @default.
- W2043445008 title "Fabrication and enhanced visible-light photocatalytic activity of carbon self-doped TiO<sub>2</sub>sheets with exposed {001} facets" @default.
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- W2043445008 doi "https://doi.org/10.1039/c0jm02217a" @default.
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