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- W2043451750 abstract "The radiolysis of D(+)-carnitine by 60Co-γ-radiation was examined to obtain optically active β-methylcholine. It was found that the radio lysis leads to a number of trimethylammonium bases but to no other betaines. The acids formed were not investigated. The bases produced were separated by ion exchange chromatography. (+)-β-Methylcholine and acetonyltrimethylammonium could be identified by means of common analytical methods (IR, NMR, MS and MA) applied to the fractions. The amounts of methylamines formed by irradiation, and determined by gas chromatography, were very small. Racemization of the D(+)-carnitine did not occur during irradiation, L(-)-carnitine was not found when an enzymatical determination method was used. The fact that (+)-β-methylcholine was formed from D(+)-carnitine is pharmacologically important, because acetyl-L(+)-β-methylcholine has a strong interaction with muscarinic receptors." @default.
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- W2043451750 date "1986-06-01" @default.
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- W2043451750 title "Radiolysis of D(+)-carnitine by 60Co-γ-radiation and formation of L(+)-β-methylcholine" @default.
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- W2043451750 doi "https://doi.org/10.1002/jlcr.2580230606" @default.
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