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- W2043453423 abstract "The influence of substances such as carboxylic acids, esters, thiol, on the rate of reaction of cyclopentanol with phenylisocyanate was studied in acetonitrile and toluene at 25°C with dibutyltin di(2-ethylhexanoate) (DBTDEH) as catalyst. Carboxylic acids induce an important rate reduction, as already observed [A.-C. Draye, J.-J. Tondeur, J. Mol. Catal. A: Chem. 138 (1999) 135; A.-C. Draye, J.-J. Tondeur, React. Kinet. Catal. Lett., submitted for publication]. The present results, dealing with the effect of added foreign substances, bring new evidences confirming Davies' reaction scheme [A.J. Bloodworth, A.G. Davies, Proc. Chem. Soc. (1963) 264; A.J. Bloodworth, A.G. Davies, J. Chem. Soc. (1965) 5238] in which the first step would be an alcoholysis of carboxylate groups of the catalyst." @default.
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- W2043453423 date "1999-03-19" @default.
- W2043453423 modified "2023-09-25" @default.
- W2043453423 title "Kinetic study of organotin catalyzed alcohol-isocyanate reactions Part 2: Inhibition by foreign substances in acetonitrile and toluene" @default.
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- W2043453423 doi "https://doi.org/10.1016/s1381-1169(98)00209-x" @default.
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