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- W2043460894 abstract "The rate of growth has been studied of the alloy layer formed on molybdenum when it is immersed in solutions of aluminium in the liquid metals, bismuth, cadmium, indium, lead, thallium or tin at 500°C. The published work on the aluminium-molybdenum phase diagram is surveyed and from this and some additional studies the compounds in the alloy layer were identified as Al3Mo, Al5Mo and Al12Mo. The only other well-established compound in the system AlMo3, was found to grow too slowly at this temperature to be observed in the layer. Considerable differences were found in the rates of growth and composition of the alloy layer in the different solvent metals. The solubilities and rates of solution of aluminium in the solvent metals were measured in order to elucidate the rate controlling step in the mass transfer and its dependence on the liquid metal. Provided that the liquid metal was saturated with aluminium in the vicinity of the molybdenum, diffusion in the solid state was the rate controlling step. However, this condition was not satisfied for those liquid metals in which aluminium was sparingly soluble (e.g. lead) and under our test conditions the rate of solution was found to be of the same order as the rate of removal of aluminium by alloying. The implications of these results on the use of liquid metals in reactor technology is discussed." @default.
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- W2043460894 date "1962-07-01" @default.
- W2043460894 modified "2023-09-25" @default.
- W2043460894 title "Isothermal mass transfer of aluminium onto molybdenum in liquid metals" @default.
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- W2043460894 doi "https://doi.org/10.1016/0368-3230(62)90191-x" @default.
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