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- W2043461835 abstract "The relativistic configuration interaction approach based on numerical wavefunctions computed with a single-configuration relativistic Hartree-Fock method is employed to calculate ionisation and excitation energies as well as oscillator strengths for the ns2 1S0-nsnp 3P1, 1P1 transitions in cadmium and mercury isoelectronic sequences. The core polarisation model is used to account for valence-core correlation influence on both wavefunctions and total energies. The results are compared with previous relativistic multiconfiguration Hartree-Fock and other theoretical data as well as with available experimental values. It is demonstrated that the proposed relativistic CI approach yields accurate and reliable data at a far smaller computational expense than required for similar scale multiconfiguration calculations. It also permits us to avoid numerous convergence problems common for the multiconfiguration approach." @default.
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- W2043461835 date "1988-06-28" @default.
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- W2043461835 title "Relativistic CI calculations for the ns<sup>2</sup><sup>1</sup>S<sub>0</sub>-nsnp<sup>3</sup>P<sub>1</sub>,<sup>1</sup>P<sub>1</sub>transitions in the cadmium and mercury isoelectronic sequences" @default.
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- W2043461835 doi "https://doi.org/10.1088/0953-4075/21/12/009" @default.
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