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- W2043485369 abstract "Abstract Ferrocenes bearing dialkylaluminum substituents in the 1,1′‐positions were characterized as their dipyridine adducts, and it was shown that they can be transformed into dinuclear alkylaluminum‐bridged [1.1]ferrocenophanes and finally into the trinuclear aluminum‐bridged ferrocenophane, both as dipyridine adducts. The synthesis of the latter compound was optimized and found to be most efficient (>40 % yield) through the reaction of 1,1′‐dilithioferrocene with MeAlCl 2 . The molecular structures of the dinuclear and trinuclear complexes were determined by X‐ray crystallography. The solution‐state structures of the new compounds were studied by multinuclear magnetic resonance methods, including 1 H– 1 H NOE difference experiments.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)" @default.
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- W2043485369 date "2009-07-01" @default.
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- W2043485369 title "1,1′‐Disubstituted Ferrocenes with Aluminum: Dinuclear and Trinuclear Dialumina[1.1]ferrocenophanes as Pyridine Adducts" @default.
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- W2043485369 doi "https://doi.org/10.1002/ejic.200900272" @default.
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