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- W2043552042 abstract "During the enzymatic synthesis of open chain ketose-1-phosphates on a preparative scale using fructose-1,6-bisphosphate aldolases from Staphylococcus carnosus a successive reaction of excess aldehyde with the primary reaction product was observed leading to the corresponding 1,3-dioxane derivatives. The thermodynamic equilibrium between aldehyde, ketose-1-phosphate and the 1,3-dioxane derivative was studied. It could be demonstrated that the enzyme is not required for the successive reaction of 2-methylpropanol or propanal with 5,6-dideoxy-5-methyl-D-threo-hexulose-1-phospate yielding the semiacetal, but the reaction rate is considerably faster and yields of 2,6-bis-(1-methylethyl)-4,5-dihydroxy-4-phosphorylmethyl-1,3-dioxane are higher if the reaction starts with dihydroxyacetone-phosphate and 2-methylpropanal in the presence of the aldolase. 1,3-dioxane formation was not observed in the enzymatic synthesis of 6-deoxy-L-sorbose-1-phosphate using a high excess of L-lactaldehyde, which was attributed to the kinetically favored cyclisation to the furanose form in water." @default.
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- W2043552042 date "2001-01-01" @default.
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- W2043552042 title "Fructose-1,6-Bisphosphate Aldolases from Staphylococcus Carnosus: Stereoselective Enzymatic Synthesis of Ketose-1-Phosphates and Successive Reaction to 1,3-Dioxanes" @default.
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- W2043552042 doi "https://doi.org/10.3109/10242420109103516" @default.
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