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- W2043631253 abstract "AN investigation by me of the Raman effect in a series of mercaptans has yielded some noteworthy results. As is well known, the mercaptans are chemically analogous to the alcohols, the SH group in them replacing the OH group characteristic of the alcohols. The oscillation of the SH group comes out prominently as an intense though somewhat diffuse line in the Raman spectra of all the mercaptans examined, with a frequency shift of 2574 wave numbers. This is in marked contrast to the behaviour of the OH group, of which the broad band (σ = 3400 cm.–1 approximately) appears only in water and methyl alcohol but not in the higher alcohols. Another strong line appears with all the mercaptans giving a frequency shift of about 657 wave numbers, and is evidently due to the oscillation of the CS group; it is in the same position as the most intense line in the spectrum of carbon disulphide. The analogous oscillation of the CO group with a frequency of about 1050 wave numbers appears strongly in methyl alcohol but only very weakly in the higher alcohols." @default.
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- W2043631253 date "1930-09-01" @default.
- W2043631253 modified "2023-09-26" @default.
- W2043631253 title "Raman Spectra of the Mercaptans" @default.
- W2043631253 doi "https://doi.org/10.1038/126434b0" @default.
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