FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2043651069> ?p ?o ?g. }

• W2043651069 endingPage "8651" @default.
• W2043651069 startingPage "8641" @default.
• W2043651069 abstract "We present a detailed discussion on infrared spectroscopy of vibrational combination bands and overtones of adsorbate systems. For the case that the (dynamical) lateral coupling between the adsorbates is dominated by dipole coupling, we present general results for the absorption spectra which can be used to analyze experimental data and deduce the bond anharmonicity δω. The theoretical results are used to analyze experimental line shape data for the combination band of the C–O and the Ru–CO stretch vibrational modes of CO adsorbed on Ru(001), as well as the overtone of the C–O stretch vibration for the same adsorbate system. It is found that for strong lateral coupling (and weak anharmonicities) asymmetric line shapes are common; strong anharmonicities lead to the formation of localized two-phonon bound states besides a continuum of delocalized two-phonon states. However, even then the extraction of anharmonic parameters can be severely impeded by dynamic line shifts of the localized overtone band through virtual transfers of vibrational quanta to neighboring oscillators. We further consider the mechanisms which contribute to the broadening of overtone excitations and show that the energy relaxation rate for the overtone is twice as large as for the fundamental, while the (pure) dephasing rate is approximately four times higher than that of the fundamental excitation." @default.
• W2043651069 created "2016-06-24" @default.
• W2043651069 creator A5005551933 @default.
• W2043651069 creator A5042679368 @default.
• W2043651069 date "1998-11-15" @default.
• W2043651069 modified "2023-10-18" @default.
• W2043651069 title "Infrared spectroscopy of overtones and combination bands" @default.
• W2043651069 cites W1965372456 @default.
• W2043651069 cites W1975898824 @default.
• W2043651069 cites W1976314729 @default.
• W2043651069 cites W1978231175 @default.
• W2043651069 cites W1979616199 @default.
• W2043651069 cites W1982954654 @default.
• W2043651069 cites W1983113015 @default.
• W2043651069 cites W1986555800 @default.
• W2043651069 cites W1992792017 @default.
• W2043651069 cites W1995762572 @default.
• W2043651069 cites W1999723361 @default.
• W2043651069 cites W2007678244 @default.
• W2043651069 cites W2016451426 @default.
• W2043651069 cites W2016681629 @default.
• W2043651069 cites W2027949676 @default.
• W2043651069 cites W2031316117 @default.
• W2043651069 cites W2031510004 @default.
• W2043651069 cites W2033014123 @default.
• W2043651069 cites W2033080992 @default.
• W2043651069 cites W2033752764 @default.
• W2043651069 cites W2036299712 @default.
• W2043651069 cites W2043222937 @default.
• W2043651069 cites W2074081055 @default.
• W2043651069 cites W2074312315 @default.
• W2043651069 cites W2075496577 @default.
• W2043651069 cites W2077221903 @default.
• W2043651069 cites W2079285530 @default.
• W2043651069 cites W2080072007 @default.
• W2043651069 cites W2080074668 @default.
• W2043651069 cites W2091453658 @default.
• W2043651069 cites W2092438291 @default.
• W2043651069 cites W3038047640 @default.
• W2043651069 cites W4233310360 @default.
• W2043651069 cites W4241921884 @default.
• W2043651069 doi "https://doi.org/10.1063/1.477531" @default.
• W2043651069 hasPublicationYear "1998" @default.
• W2043651069 type Work @default.
• W2043651069 sameAs 2043651069 @default.
• W2043651069 citedByCount "76" @default.
• W2043651069 countsByYear W20436510692012 @default.
• W2043651069 countsByYear W20436510692013 @default.
• W2043651069 countsByYear W20436510692014 @default.
• W2043651069 countsByYear W20436510692015 @default.
• W2043651069 countsByYear W20436510692016 @default.
• W2043651069 countsByYear W20436510692017 @default.
• W2043651069 countsByYear W20436510692018 @default.
• W2043651069 countsByYear W20436510692019 @default.
• W2043651069 countsByYear W20436510692021 @default.
• W2043651069 countsByYear W20436510692022 @default.
• W2043651069 crossrefType "journal-article" @default.
• W2043651069 hasAuthorship W2043651069A5005551933 @default.
• W2043651069 hasAuthorship W2043651069A5042679368 @default.
• W2043651069 hasConcept C120665830 @default.
• W2043651069 hasConcept C121332964 @default.
• W2043651069 hasConcept C124806180 @default.
• W2043651069 hasConcept C147724859 @default.
• W2043651069 hasConcept C153642686 @default.
• W2043651069 hasConcept C158355884 @default.
• W2043651069 hasConcept C173523689 @default.
• W2043651069 hasConcept C178790620 @default.
• W2043651069 hasConcept C181500209 @default.
• W2043651069 hasConcept C184779094 @default.
• W2043651069 hasConcept C185592680 @default.
• W2043651069 hasConcept C24123453 @default.
• W2043651069 hasConcept C26873012 @default.
• W2043651069 hasConcept C32891209 @default.
• W2043651069 hasConcept C32909587 @default.
• W2043651069 hasConcept C38615331 @default.
• W2043651069 hasConcept C41999313 @default.
• W2043651069 hasConcept C4839761 @default.
• W2043651069 hasConcept C49023278 @default.
• W2043651069 hasConcept C62520636 @default.
• W2043651069 hasConcept C70050531 @default.
• W2043651069 hasConcept C84662259 @default.
• W2043651069 hasConceptScore W2043651069C120665830 @default.
• W2043651069 hasConceptScore W2043651069C121332964 @default.
• W2043651069 hasConceptScore W2043651069C124806180 @default.
• W2043651069 hasConceptScore W2043651069C147724859 @default.
• W2043651069 hasConceptScore W2043651069C153642686 @default.
• W2043651069 hasConceptScore W2043651069C158355884 @default.
• W2043651069 hasConceptScore W2043651069C173523689 @default.
• W2043651069 hasConceptScore W2043651069C178790620 @default.
• W2043651069 hasConceptScore W2043651069C181500209 @default.
• W2043651069 hasConceptScore W2043651069C184779094 @default.
• W2043651069 hasConceptScore W2043651069C185592680 @default.
• W2043651069 hasConceptScore W2043651069C24123453 @default.
• W2043651069 hasConceptScore W2043651069C26873012 @default.
• W2043651069 hasConceptScore W2043651069C32891209 @default.
• W2043651069 hasConceptScore W2043651069C32909587 @default.
• W2043651069 hasConceptScore W2043651069C38615331 @default.
• W2043651069 hasConceptScore W2043651069C41999313 @default.

• next