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- W2043669604 abstract "A special case of liquid-liquid extraction as been considered where the solute on absorption reacts to form a dimer through a rapid second order reversible reaction with the solvent. If dimer and monomer have different diffusivities (in the same solvent) the rate of absorption becomes dependent on the ratio of these diffusivities and the isotherm governing the “association” reaction. The non linear differential equation governing the absorption was solved numerically with the aid of a digital computer for the case of resistance in one phase only. Correlations based on these solutions were then used in formulating a rate equation. Methods were suggested for the determination of the quantities occurring in the “driving force” of the predicted rate equation." @default.
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- W2043669604 title "Liquid-liquid extraction with association effects" @default.
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